The Hurt Locker which was shot on 16, and its a great way to learn the craft.
Yeah, loading any 16mm camera with 16mm film will make it look like hollywood... just like the HDSLR's!
Seriously. Film is a whole other craft. There are so many aspects that will require a level of knowledge and skill about the actual craft that I would personally never attempt 16/35 without attending film school. Otherwise it's most likely a waste of your time and MONEY, if you have film ambitions buy an 8mm and start there.