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Like Legreved says, the Samyang's are pretty warm which i don't like. They are the best bang for the buck, but yeah, I still prefer my Zeiss and Canon Ls because of the color which are more delineated IMO. The Samyangs are like Sigma, they are noticeably skewed towards yellows which is not desirable, at least for me. I ended up selling my 35mm and got the Zeiss 35mm f2, but yeah... way more money. For the cash, Samyangs are really good.
Nikon mount:Where did you find the set of Rokinon Cine Lenses?
the e-mount has a really shallow flange distance - length from sensor to lens mount. bear in mind that you will get a new camera some day - for example if you buy a canon camera, you could use your Rokinons wih Nikon mount (via canon-nikon adapter), but you won't be able to use your E-mount lenses on a canon camera since the flange distance won't match the lens-camera combo, and can't be matched via an adapter. Future proof your gear, i suppose you don't want to buy a new set of lenses each time you buy a new camera.
All manual adjustments, no electronic control.
Peaking has nothing to do with the lens and will work.
Regarding your questions about Nikon mount, many people standardise on Nikon mount because: 1. They have existing Nikon Lenses. 2. The quality is high. 3. They can be adapted to almost any camera (at least in manual mode). 4. Many older Nikon lenses (not all) have a real f-stop ring (iris). Somewhat the same answer would be true of Canon lenses.